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This is Ambrosia, a special variant of Pokemon known in http://PKMNation.deviantart.com as a Rarity! She's constantly scheming and is frequently followed around by Golden! They'd have a Pinky & The Brain dynamic going on if Ambrosia was more evil!

Art (c) galacticpink
Originally Designed by http://Headsmashscrafty.deviantart.com
PKMNation (c) http://pkmnation.deviantart.com
Pokemon (c) Nintendo